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  2. High harmonic generation - Wikipedia

    en.wikipedia.org/wiki/High_Harmonic_Generation

    High harmonic generation strongly depends on the driving laser field and as a result the harmonics have similar temporal and spatial coherence properties. [10] High harmonics are often generated with pulse durations shorter than that of the driving laser. [11] This is due to the nonlinearity of the generation process, phase matching and ...

  3. Attosecond physics - Wikipedia

    en.wikipedia.org/wiki/Attosecond_physics

    High harmonic generation in krypton.This technology is one of the most used techniques to generate attosecond bursts of light. Attosecond physics, also known as attophysics, or more generally attosecond science, is a branch of physics that deals with light-matter interaction phenomena wherein attosecond (10 −18 s) photon pulses are used to unravel dynamical processes in matter with ...

  4. Molecular Hamiltonian - Wikipedia

    en.wikipedia.org/wiki/Molecular_Hamiltonian

    The corresponding Schrödinger equation is easily solved, it factorizes into 3N − 6 equations for one-dimensional harmonic oscillators. The main effort in this approximate solution of the nuclear motion Schrödinger equation is the computation of the Hessian F of V and its diagonalization.

  5. Ultrafast laser spectroscopy - Wikipedia

    en.wikipedia.org/wiki/Ultrafast_laser_spectroscopy

    High harmonic generation (HHG) is a nonlinear process where intense laser radiation is converted from one fixed frequency to high harmonics of that frequency by ionization and recollision of an electron. It was first observed in 1987 by McPherson et al. who successfully generated harmonic emission up to the 17th order at 248 nm in neon gas. [3]

  6. Harmonic generation - Wikipedia

    en.wikipedia.org/wiki/Harmonic_generation

    N-th harmonic generation. Harmonic generation (HG, also called multiple harmonic generation) is a nonlinear optical process in which photons with the same frequency interact with a nonlinear material, are "combined", and generate a new photon with times the energy of the initial photons (equivalently, times the frequency and the wavelength divided by ).

  7. Overtone band - Wikipedia

    en.wikipedia.org/wiki/Overtone_band

    In vibrational spectroscopy, an overtone band is the spectral band that occurs in a vibrational spectrum of a molecule when the molecule makes a transition from the ground state (v=0) to the second excited state (v=2), where v is the vibrational quantum number (a non-negative integer) obtained from solving the Schrödinger equation for the molecule.

  8. GF method - Wikipedia

    en.wikipedia.org/wiki/GF_method

    In Wilson's GF method it is assumed that the molecular kinetic energy consists only of harmonic vibrations of the atoms, i.e., overall rotational and translational energy is ignored. Normal coordinates appear also in a quantum mechanical description of the vibrational motions of the molecule and the Coriolis coupling between rotations and ...

  9. Wavenumber - Wikipedia

    en.wikipedia.org/wiki/Wavenumber

    Diagram illustrating the relationship between the wavenumber and the other properties of harmonic waves. In the physical sciences, the wavenumber (or wave number), also known as repetency, [1] is the spatial frequency of a wave, measured in cycles per unit distance (ordinary wavenumber) or radians per unit distance (angular wavenumber).