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  2. Trigonal pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_pyramidal...

    This would result in the geometry of a regular tetrahedron with each bond angle equal to arccos(− ⁠ 1 / 3 ⁠) ≈ 109.5°. However, the three hydrogen atoms are repelled by the electron lone pair in a way that the geometry is distorted to a trigonal pyramid (regular 3-sided pyramid) with bond angles of 107°.

  3. Square pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Square_pyramidal_molecular...

    Structure of xenon oxytetrafluoride, an example of a molecule with the square pyramidal coordination geometry. Square pyramidal geometry describes the shape of certain chemical compounds with the formula ML 5 where L is a ligand. If the ligand atoms were connected, the resulting shape would be that of a pyramid with a square base.

  4. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    Relativistic effects on the electron orbitals of superheavy elements is predicted to influence the molecular geometry of some compounds. For instance, the 6d 5/2 electrons in nihonium play an unexpectedly strong role in bonding, so NhF 3 should assume a T-shaped geometry, instead of a trigonal planar geometry like its lighter congener BF 3. [38]

  5. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule. It includes the general shape of the molecule as well as bond lengths , bond angles , torsional angles and any other geometrical parameters that determine the position of each atom.

  6. Pentagonal pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Pentagonal_pyramidal...

    In chemistry, pentagonal pyramidal molecular geometry describes the shape of compounds where in six atoms or groups of atoms or ligands are arranged around a central atom, at the vertices of a pentagonal pyramid. It is one of the few molecular geometries with uneven bond angles. [1] AX 6 E 1

  7. Category:Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Category:Molecular_geometry

    Download as PDF; Printable version; ... Pages in category "Molecular geometry" ... Pentagonal pyramidal molecular geometry; Point group;

  8. Berry mechanism - Wikipedia

    en.wikipedia.org/wiki/Berry_mechanism

    Trigonal bipyramidal molecular shape ax = axial ligands (on unique axis) eq = equatorial ligand (in plane perpendicular to unique axis). The Berry mechanism, or Berry pseudorotation mechanism, is a type of vibration causing molecules of certain geometries to isomerize by exchanging the two axial ligands (see the figure) for two of the equatorial ones.

  9. Capped square antiprismatic molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Capped_square_anti...

    In chemistry, the capped square antiprismatic molecular geometry describes the shape of compounds where nine atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a gyroelongated square pyramid. The symmetry group of the resulting object is C 4v