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Another high-temperature lubricant, hexagonal boron nitride, has the same molecular structure as graphite. It is sometimes called white graphite, due to its similar properties. When a large number of crystallographic defects bind its planes together, graphite loses its lubrication properties and becomes what is known as pyrolytic graphite.
Calcium graphite CaC 6 is obtained by immersing highly oriented pyrolytic graphite in liquid Li–Ca alloy for 10 days at 350 °C. The crystal structure of CaC 6 belongs to the R 3 m space group. The graphite interlayer distance increases upon Ca intercalation from 3.35 to 4.524 Å, and the carbon-carbon distance increases from 1.42 to 1.444 Å.
The Laves graph or K 4 crystal is a theoretically predicted three-dimensional crystalline metastable carbon structure in which each carbon atom is bonded to three others, at 120° angles (like graphite), but where the bond planes of adjacent layers lie at an angle of 70.5°, rather than coinciding.
The structure of graphite was identified in 1916 [7] by the related method of powder diffraction. [8] It was studied in detail by Kohlschütter and Haenni in 1918, who described the properties of graphite oxide paper. [9] Its structure was determined from single-crystal diffraction in 1924. [10] The theory of graphene was first explored by P. R ...
The structure and properties of graphite oxide depend on the particular synthesis method and degree of oxidation. [11] [12] It typically preserves the layer structure of the parent graphite, but the layers are buckled and the interlayer spacing is about two times larger (~0.7 nm) than that of graphite. Strictly speaking "oxide" is an incorrect ...
In physics, Dirac cones are features that occur in some electronic band structures that describe unusual electron transport properties of materials like graphene and topological insulators. [ 1 ] [ 2 ] [ 3 ] In these materials, at energies near the Fermi level , the valence band and conduction band take the shape of the upper and lower halves ...
Graphitization can be observed in various contexts. For example, it occurs naturally during the formation of certain types of coal or graphite in the Earth's crust.It can also be artificially induced during the manufacture of specific carbon materials, such as graphite electrodes used in fuel cells, nuclear reactors or metallurgical applications.
To produce expandable graphite, natural graphite flakes are treated in a bath of acid and oxidizing agent.Usually used oxidizing agents are hydrogen peroxide, potassium permanganate or chromic acid. Concentrated sulphuric acid or nitric acid are usually used as the compound to be incorporated, with the reaction taking place at temperatures of ...