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A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
The solid/liquid/vapor triple point of liquid water, ice I h and water vapor in the lower left portion of a water phase diagram. The temperature and pressure at which ordinary solid, liquid, and gaseous water coexist in equilibrium is a triple point of water.
Triple points mark conditions at which three different phases can coexist. For example, the water phase diagram has a triple point corresponding to the single temperature and pressure at which solid, liquid, and gaseous water can coexist in a stable equilibrium (273.16 K and a partial vapor pressure of 611.657 Pa).
At the triple point, all three phases can coexist. However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the critical point. The critical point of water occurs at 647.096 K (373.946 °C; 705.103 °F) and 22.064 megapascals (3,200.1 psi; 217.75 atm; 220.64 bar). [3]
In the diagram for CO 2 the triple point is the point at which the solid, liquid and gas phases come together, at 5.2 bar and 217 K. It is also possible for other sets of phases to form a triple point, for example in the water system there is a triple point where ice I, ice III and liquid can coexist.
At triple point. An important basic value, which is not registered in the table, is the saturated vapor pressure at the triple point of water. The internationally accepted value according to measurements of Guildner, Johnson and Jones (1976) amounts to: P w (t tp = 0.01 °C) = 611.657 Pa ± 0.010 Pa at (1 − α) = 99%
Increasing the pressure drives the water into the higher density phase, which causes melting. Another interesting though not unusual feature of the phase diagram is the point where the solid–liquid phase line meets the liquid–gas phase line. The intersection is referred to as the triple point. At the triple point, all three phases can coexist.
Ice, water, and water vapour can coexist at the triple point, which is exactly 273.16 K (0.01 °C) at a pressure of 611.657 Pa. [14] [15] The kelvin was defined as 1 / 273.16 of the difference between this triple point and absolute zero, [16] though this definition changed in May 2019. [17] Unlike most other solids, ice is difficult to ...