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The bromine cycle is a biogeochemical cycle of bromine through the atmosphere, biosphere, and hydrosphere. ... which release gaseous bromine. Anthropogenic sources
Bromine's chemistry is linked to other halogens such as chlorine and iodine amplify atmospheric cycling that contributes to troposphere and stratosphere ozone layer destruction. Figure modified from Saiz-Lopez, A., von Glasow, R., 2012.
Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X 2 /X − couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V).
Since their discovery in the late 1980s, research on these ozone depletion events has shown the central role of bromine photochemistry. The exact sources and mechanisms that release bromine are still not fully understood, but the combination of concentrated sea salt in a condensed phase substrate appears to be a pre-requisite. [7]
Industrially, it is mainly produced by the reaction of hydrogen gas with bromine gas at 200–400 °C with a platinum catalyst. However, reduction of bromine with red phosphorus is a more practical way to produce hydrogen bromide in the laboratory: [2] 2 P + 6 H 2 O + 3 Br 2 → 6 HBr + 2 H 3 PO 3 H 3 PO 3 + H 2 O + Br 2 → 2 HBr + H 3 PO 4
1.4 Life-cycle impact assessment of lead-free solder. ... X-ray fluorescence spectroscopy can confirm the presence of bromine ... they release energy as photons. The ...
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Vanadium bromoperoxidases have been found in bacteria, fungi, marine macro algae (), and marine microalgae which produce brominated organic compounds. [2]It has not been definitively identified as the bromoperoxidase of higher eukaryotes, such as murex snails, which have a very stable and specific bromoperoxidase, but perhaps not a vanadium dependent one. [3]