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Atomic diffusion in polycrystalline materials is therefore often modeled using an effective diffusion coefficient, which is a combination of lattice, and grain boundary diffusion coefficients. In general, surface diffusion occurs much faster than grain boundary diffusion , and grain boundary diffusion occurs much faster than lattice diffusion .
Surface diffusion, also referred to as atomic diffusion, describes the process along the surface interface, when atoms move from surface to surface to free energy. The grain boundary diffusion terms the free migration of atoms in free atomic lattice spaces. This is based on polycrystalline layers and its boundaries of incomplete matching of the ...
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Atomic diffusion on the surface of a crystal. The shaking of the atoms is an example of thermal fluctuations. Likewise, thermal fluctuations provide the energy necessary for the atoms to occasionally hop from one site to a neighboring one. For simplicity, the thermal fluctuations of the blue atoms are not shown.
The word diffusion derives from the Latin word, diffundere, which means "to spread out". A distinguishing feature of diffusion is that it depends on particle random walk, and results in mixing or mass transport without requiring directed bulk motion. Bulk motion, or bulk flow, is the characteristic of advection. [1]
Interstitial Atomic diffusion across a 4-coordinated lattice. Note that the atoms often block each other from moving to adjacent sites. As per Fick’s law, the net flux (or movement of atoms) is always in the opposite direction of the concentration gradient.
Atomic weight: M: chemistry (mass of one atom divided by the atomic mass constant, 1 Da) Bodenstein number: Bo or Bd = / = chemistry (residence-time distribution; similar to the axial mass transfer Peclet number) [2] Damkohler number: Da =
The Kirkendall effect is the motion of the interface between two metals that occurs due to the difference in diffusion rates of the metal atoms. The effect can be observed, for example, by placing insoluble markers at the interface between a pure metal and an alloy containing that metal, and heating to a temperature where atomic diffusion is reasonable for the given timescale; the boundary ...