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For a heat engine, thermal efficiency is the ratio of the net work output to the heat input; in the case of a heat pump, thermal efficiency (known as the coefficient of performance or COP) is the ratio of net heat output (for heating), or the net heat removed (for cooling) to the energy input (external work). The efficiency of a heat engine is ...
A reversible heat engine with a low efficiency delivers more heat (energy) to the hot reservoir for a given amount of work (energy) to this engine when it is being driven as a heat pump. All these mean that heat can transfer from cold to hot places without external work, and such a heat transfer is impossible by the second law of thermodynamics .
By the principle of minimum energy, there are a number of other state functions which may be defined which have the dimensions of energy and which are minimized according to the second law under certain conditions other than constant entropy. These are called thermodynamic potentials. For each such potential, the relevant fundamental equation ...
A realistic indication of energy efficiency over an entire year can be achieved by using seasonal COP or seasonal coefficient of performance (SCOP) for heat. Seasonal energy efficiency ratio (SEER) is mostly used for air conditioning. SCOP is a new methodology that gives a better indication of expected real-life performance, using COP can be ...
90–95% (multiply by the energy efficiency of electricity generation to compare with other water-heating systems) Electric heater: Electrical to thermal ~100% (essentially all energy is converted into heat, multiply by the energy efficiency of electricity generation to compare with other heating systems) Others: Firearm: Chemical to kinetic
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The statement of Newton's law used in the heat transfer literature puts into mathematics the idea that the rate of heat loss of a body is proportional to the difference in temperatures between the body and its surroundings. For a temperature-independent heat transfer coefficient, the statement is:
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