Search results
Results from the WOW.Com Content Network
In mathematics, the inverse trigonometric functions (occasionally also called antitrigonometric, [1] cyclometric, [2] or arcus functions [3]) are the inverse functions of the trigonometric functions, under suitably restricted domains.
Cis and trans descriptors are not used for cases of conformational isomerism where the two geometric forms easily interconvert, such as most open-chain single-bonded structures; instead, the terms "syn" and "anti" are used. According to IUPAC, "geometric isomerism" is an obsolete synonym of "cis–trans isomerism". [2]
syn/anti peri/clinal. a torsion angle between 0° and ±90° is called syn (s) a torsion angle between ±90° and 180° is called anti (a) a torsion angle between 30° and 150° or between −30° and −150° is called clinal (c) a torsion angle between 0° and ±30° or ±150° and 180° is called periplanar (p)
The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction. The type of addition that occurs depends on multiple different factors of a reaction, and is defined by the final orientation of the substituents on the parent molecule .
Anti-periplanar geometry will put a bonding orbital and an anti-bonding orbital approximately parallel to each other, or syn-periplanar. Figure 6 is another representation of 2-chloro-2,3-dimethylbutane (Figure 5), showing the C–H bonding orbital, σ C–H, and the C–Cl anti-bonding orbital, σ* C–Cl, syn-periplanar.
In mathematics, and especially in category theory, a commutative diagram is a diagram of objects, also known as vertices, and morphisms, also known as arrows or edges, such that when selecting two objects any directed path through the diagram leads to the same result by composition.
Get AOL Mail for FREE! Manage your email like never before with travel, photo & document views. Personalize your inbox with themes & tabs. You've Got Mail!
The syn-conformation shown above, with a dihedral angle of 60° is less stable than the anti-conformation with a dihedral angle of 180°. For macromolecular usage the symbols T, C, G +, G −, A + and A − are recommended (ap, sp, +sc, −sc, +ac and −ac respectively).