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Cohesion, along with adhesion (attraction between unlike molecules), helps explain phenomena such as meniscus, surface tension and capillary action. Mercury in a glass flask is a good example of the effects of the ratio between cohesive and adhesive forces.
The forces that cause adhesion and cohesion can be divided into several types. The intermolecular forces responsible for the function of various kinds of stickers and sticky tape fall into the categories of chemical adhesion , dispersive adhesion , and diffusive adhesion .
The source of adhesive forces, according to the dispersive adhesion mechanism, is the weak interactions that occur between molecules close together. [2] These interactions include London dispersion forces, Keesom forces, Debye forces and hydrogen bonds. Individually, these attractions are not very strong, but when summed over the bulk of a ...
There is also a tension parallel to the surface at the liquid-air interface which will resist an external force, due to the cohesive nature of water molecules. [2] [3] The forces of attraction acting between molecules of the same type are called cohesive forces, while those acting between molecules of different types are called adhesive forces.
The adhesive forces are usually based on physical interactions, for example, such as those between polar or polarisable groups, on hydrogen bonds, or van der Waals forces. When bonding plastics, in particular with solvent-based adhesives, diffusion processes can also play a role. In this case, the plastic at the substrate surface is dissolved ...
The contact angle is determined by the balance between adhesive and cohesive forces. As the tendency of a drop to spread out over a flat, solid surface increases, the contact angle decreases. Thus, the contact angle provides an inverse measure of wettability. [7] [8]
The adhesive is applied to either one or both of the materials being bonded. The pieces are aligned and pressure is added to aid in adhesion and rid the bond of air bubbles. Common ways of applying an adhesive include brushes, rollers, using films or pellets, spray guns and applicator guns (e.g., caulk gun). All of these can be used manually or ...
Adhesive wear is caused by relative motion, "direct contact" and plastic deformation which create wear debris and material transfer from one surface to another. Cohesive adhesive forces, holds two surfaces together even though they are separated by a measurable distance, with or without any actual transfer of material.