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A cooling curve of naphthalene from liquid to solid. A cooling curve is a line graph that represents the change of phase of matter, typically from a gas to a solid or a liquid to a solid. The independent variable (X-axis) is time and the dependent variable (Y-axis) is temperature. [1] Below is an example of a cooling curve used in castings.
It expresses the response of entropy to an increase in energy. If a small amount of energy is added to the system, then β describes the amount the system will randomize. Via the statistical definition of temperature as a function of entropy, the coldness function can be calculated in the microcanonical ensemble from the formula
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125
The law holds well for forced air and pumped liquid cooling, where the fluid velocity does not rise with increasing temperature difference. Newton's law is most closely obeyed in purely conduction-type cooling. However, the heat transfer coefficient is a function of the temperature difference in natural convective (buoyancy driven) heat transfer.
Inside the chamber, the 3 He is diluted as it flows from the concentrated phase through the phase boundary into the dilute phase. The heat necessary for the dilution is the useful cooling power of the refrigerator, as the process of moving the 3 He through the phase boundary is endothermic and removes heat from the mixing chamber environment.
There is also the peritectoid, a point where two solid phases combine into one solid phase during cooling. The inverse of this, when one solid phase transforms into two solid phases during cooling, is called the eutectoid. A complex phase diagram of great technological importance is that of the iron–carbon system for less than 7% carbon (see ...
A plot of typical polymer solution phase behavior including two critical points: a LCST and an UCST. The liquid–liquid critical point of a solution, which occurs at the critical solution temperature, occurs at the limit of the two-phase region of the phase diagram. In other words, it is the point at which an infinitesimal change in some ...
Bose–Einstein condensate: A phase in which a large number of bosons all inhabit the same quantum state, in effect becoming one single wave/particle. This is a low-energy phase that can only be formed in laboratory conditions and at very low temperatures. It must be close to absolute zero.