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Iron shows the characteristic chemical properties of the transition metals, namely the ability to form variable oxidation states differing by steps of one and a very large coordination and organometallic chemistry: indeed, it was the discovery of an iron compound, ferrocene, that revolutionalized the latter field in the 1950s. [59]
Iron shows the characteristic chemical properties of the transition metals, namely the ability to form variable oxidation states differing by steps of one and a very large coordination and organometallic chemistry: indeed, it was the discovery of an iron compound, ferrocene, that revolutionalized the latter field in the 1950s. [1]
Iron(II) chloride tetrahydrate, FeCl 2 ·4H 2 O. In chemistry, iron(II) refers to the element iron in its +2 oxidation state. The adjective ferrous or the prefix ferro-is often used to specify such compounds, as in ferrous chloride for iron(II) chloride (FeCl 2). The adjective ferric is used instead for iron(III) salts, containing the cation Fe 3+.
Iron oxides and oxyhydroxides are widespread in nature and play an important role in many geological and biological processes. They are used as iron ores, pigments, catalysts, and in thermite, and occur in hemoglobin. Iron oxides are inexpensive and durable pigments in paints, coatings and colored concretes.
Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture.Rust consists of hydrous iron(III) oxides (Fe 2 O 3 ·nH 2 O) and iron(III) oxide-hydroxide (FeO(OH), Fe(OH) 3), and is typically associated with the corrosion of refined iron.
In industry, iron(III) chloride is used as a catalyst for the reaction of ethylene with chlorine, forming ethylene dichloride (1,2-dichloroethane): [43] H 2 C=CH 2 + Cl 2 → ClCH 2 CH 2 Cl. Ethylene dichloride is a commodity chemical, which is mainly used for the industrial production of vinyl chloride, the monomer for making PVC. [44]
Potassium ferrioxalate contains the iron(III) complex [Fe(C 2 O 4) 3] 3−. In chemistry, iron(III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron(III) chloride (FeCl 3). The adjective ferrous is used instead for iron(II) salts, containing the cation Fe 2+.
Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe 2 O 3. It occurs in nature as the mineral hematite , which serves as the primary source of iron for the steel industry. It is also known as red iron oxide , especially when used in pigments .