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Dimethyldichlorosilane is a tetrahedral organosilicon compound with the formula Si(CH 3) 2 Cl 2. At room temperature it is a colorless liquid that readily reacts with water to form both linear and cyclic Si-O chains. Dimethyldichlorosilane is made on an industrial scale as the principal precursor to dimethylsilicone and polysilane compounds.
2 CH 3 Cl + Si → (CH 3) 4−n SiCl n + other products While this reaction is the standard in industrial silicone production and is nearly identical to the first direct synthesis of methyltrichlorosilane, the overall process is inefficient with respect to methyltrichlorosilane. [ 2 ]
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
Thus a relative density less than one relative to water means that the substance floats in water. The density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Increasing the pressure on an object decreases the volume of the object and thus increases its density.
This group consists of three methyl groups bonded to a silicon atom [−Si(CH 3) 3], which is in turn bonded to the rest of a molecule. This structural group is characterized by chemical inertness and a large molecular volume , which makes it useful in a number of applications.
rn(si(ch 3) 3) 2 + h 2 o → o(si(ch 3) 3) 2 + rnh 2 where X is a halogen and R is an alkyl . This method has been extended to aminomethylation via the reagent CH 3 OCH 2 N(Si(CH 3 ) 3 ) 2 , which contains a displaceable methoxy group CH 3 O –.
CH 3 SiCl 3 + 3 CH 3 OH → CH 3 Si(OCH 3) 3 + 3 HCl. Alcoholysis of alkylchlorosilanes typically proceeds via an S N 2 mechanism. Inversion of the configuration is favored during nucleophilic attack when displacing good leaving groups, such as chloride. [3] In contrast, displacement of poor leaving groups, such as alkoxide, retention is ...
Trifluoromethyltrimethylsilane (known as Ruppert-Prakash reagent, TMSCF 3) is an organosilicon compound with the formula CF 3 Si(CH 3) 3. It is a colorless liquid. It is a colorless liquid. The compound is a reagent used in organic chemistry for the introduction of the trifluoromethyl group .