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Energy profile (chemistry) In theoretical chemistry, an energy profile is a theoretical representation of a chemical reaction or process as a single energetic pathway as the reactants are transformed into products. This pathway runs along the reaction coordinate, which is a parametric curve that follows the pathway of the reaction and indicates ...
An energy profile of an exothermic reaction. In an exothermic reaction, by definition, the enthalpy change has a negative value: ΔH = H products - H reactants < 0. where a larger value (the higher energy of the reactants) is subtracted from a smaller value (the lower energy of the products). For example, when hydrogen burns: 2H 2 (g) + O 2 (g ...
In thermodynamics, an exothermic process (from Ancient Greek έξω (éxō) 'outward' and θερμικός (thermikós) 'thermal') [1] is a thermodynamic process or reaction that releases energy from the system to its surroundings, [2] usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity (e.g. a ...
An endothermic process is a chemical or physical process that absorbs heat from its surroundings. [1] In terms of thermodynamics and thermochemistry, it is a thermodynamic process with an increase in the enthalpy H (or internal energy U) of the system. [2] In an endothermic process, the heat that a system absorbs is thermal energy transfer into ...
This can be explained with reference to potential energy diagrams: Energy diagrams showing how to interpret Hammond's Postulate. In case (a), which is an exothermic reaction, the energy of the transition state is closer in energy to that of the reactant than that of the intermediate or the product.
The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH⊖, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book ...
The enthalpy of solution is most often expressed in kJ / mol at constant temperature. The energy change can be regarded as being made up of three parts: the endothermic breaking of bonds within the solute and within the solvent, and the formation of attractions between the solute and the solvent. An ideal solution has a null enthalpy of mixing.
A thermochemical equation is a balanced stoichiometric chemical equation that represents the energy changes from a system to its surroundings. One such equation involves the enthalpy change, which is denoted with ΔH. In variable form, a thermochemical equation would appear similar to the following: A + B → C. ΔH = (±) #.