Search results
Results from the WOW.Com Content Network
In stereochemistry, diastereomers (sometimes called diastereoisomers) are a type of stereoisomer. [1] Diastereomers are defined as non-mirror image, non-identical stereoisomers. Hence, they occur when two or more stereoisomers of a compound have different configurations at one or more (but not all) of the equivalent (related) stereocenters and ...
A meso compound or meso isomer is an optically inactive isomer in a set of stereoisomers, at least two of which are optically active. [1][2] This means that despite containing two or more stereocenters, the molecule is not chiral. A meso compound is superposable on its mirror image (not to be confused with superimposable, as any two objects can ...
A meso compound is superposable on its mirror image, therefore it reduces the number of stereoisomers predicted by the 2 n rule. This occurs because the molecule obtains a plane of symmetry that causes the molecule to rotate around the central carbon–carbon bond. [12] One example is meso-tartaric acid, in which (R,S) is the same as the (S,R ...
The stereochemical term diastereotopic refers to the relationship between two groups in a molecule which, if replaced, would generate compounds that are diastereomers. Diastereotopic groups are often, but not always, identical groups attached to the same atom in a molecule containing at least one chiral center.
2,3-Butanediamines can be prepared by hydrolyzing 2-ethoxy-4,5-dihydro-4,5-dimethylimidazole with barium hydroxide. [4] Alternative, it is produced by reduction of dimethylglyoxime with lithium aluminium hydride. [5] The meso and the d,l diastereomers can be separated by fractional crystallization of the hydrochlorides.
Stereochemistry focuses on stereoisomers, red boxes in the picture. In stereochemistry, stereoisomerism, or spatial isomerism, is a form of isomerism in which molecules have the same molecular formula and sequence of bonded atoms (constitution), but differ in the three-dimensional orientations of their atoms in space. [1][2] This contrasts with ...
Stereocenter. In stereochemistry, a stereocenter of a molecule is an atom (center), axis or plane that is the focus of stereoisomerism; that is, when having at least three different groups bound to the stereocenter, interchanging any two different groups creates a new stereoisomer. [ 1 ][ 2 ] Stereocenters are also referred to as stereogenic ...
Tacticity (from Greek: τακτικός, romanized: taktikos, "relating to arrangement or order") is the relative stereochemistry of adjacent chiral centers within a macromolecule. [1] The practical significance of tacticity rests on the effects on the physical properties of the polymer. The regularity of the macromolecular structure influences ...