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Diborane(4) is a transient inorganic compound with the chemical formula B 2 H 4.Stable derivatives are known. Diborane(4) has been produced by abstraction of two hydrogen atoms from diborane(6) using atomic fluorine and detected by photoionization mass spectrometry. [1]
The styx rule, also known as Lipscomb's styx rule, can be used to calculate the structures of boranes.It was developed by William Lipscomb in 1954. [1] The rule defines boranes to have four types of bonds besides the terminal B-H bonds: [2]
The development of the chemistry of boranes led to innovations in synthetic methods as well as structure and bonding. First, new synthetic techniques were required to handle diborane and many of its derivatives, which are both pyrophoric and volatile.
Molecular species BH 3 is a very strong Lewis acid. It can be isolated in the form of various adducts, such as borane carbonyl, BH 3 (CO). [11] Molecular BH 3 is believed to be a reaction intermediate in the pyrolysis of diborane to produce higher boranes: [5] B 2 H 6 ⇌ 2BH 3 BH 3 +B 2 H 6 → B 3 H 7 +H 2 (rate determining step) BH 3 + B 3 H ...
Diborane(6), commonly known as diborane, is the chemical compound with the formula B 2 H 6.It is a highly toxic, colorless, and pyrophoric gas with a repulsively sweet odor. . Given its simple formula, borane is a fundamental boron compou
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Recent improvements in the synthesis of tetrahalodiboranes has yielded more convenient solution phase syntheses of B 2 F 4, B 2 Cl 4, B 2 Br 4, and B 2 I 4. [3] The solution phase synthesis of B 2 Br 4 first reported by Noth et al in 1981 has not been improved upon. To form B 2 Br 4 in solution, B 2 (OMe) 4 is treated with BBr 3. [3]