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The magnitude of the equilibrium constant depends on the Gibbs free energy change for the reaction. [2] So, when the free energy change is large (more than about 30 kJ mol −1), the equilibrium constant is large (log K > 3) and the concentrations of the reactants at equilibrium are very small. Such a reaction is sometimes considered to be an ...
Reversible adiabatic process: The state on the left can be reached from the state on the right as well as vice versa without exchanging heat with the environment. In some cases, it may be important to distinguish between reversible and quasistatic processes. Reversible processes are always quasistatic, but the converse is not always true. [2]
The concept of chemical equilibrium was developed in 1803, after Berthollet found that some chemical reactions are reversible. [4] For any reaction mixture to exist at equilibrium, the rates of the forward and backward (reverse) reactions must be equal. In the following chemical equation, arrows point both ways to indicate equilibrium. [5]
Phosphorylation occurs when a PO 3 (phosphoryl) group is added to a protein. [3] This chemical modification is the most extensively studied and is reversible. The result of those studies has shown that phosphorylation acts as a regulator for proteins in two ways: the addition or removal of phosphoryl group can impact enzyme kinetics by turning on or off the enzymatic function via ...
Cato Maximilian Guldberg and Peter Waage, building on Claude Louis Berthollet's ideas [4] [5] about reversible chemical reactions, proposed the law of mass action in 1864. [ 6 ] [ 7 ] [ 8 ] These papers, in Danish, went largely unnoticed, as did the later publication (in French) of 1867 which contained a modified law and the experimental data ...
Equations of mechanics are reversible in time, hence, the reverse collisions obey the same laws. This reversibility of collisions is the first example of microreversibility. According to Boltzmann, this microreversibility implies the principle of detailed balance for collisions: at the equilibrium ensemble each collision is equilibrated by its ...
In chemistry, chromism is a process that induces a change, often reversible, in the colors of compounds.In most cases, chromism is based on a change in the electron states of molecules, especially the π- or d-electron state, so this phenomenon is induced by various external stimuli which can alter the electron density of substances.
While free energy change describes the stability of products relative to reactants, the rate of any reaction is defined by the energy of the transition state relative to the starting material. Depending on these parameters, a reaction can be favorable or unfavorable, fast or slow and reversible or irreversible, as shown in figure 8.