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Lewis dot structure of a Hydroxide ion compared to a hydroxyl radical. In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. [1] [2] With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most ...
For a positive real number x, denotes the positive square root of x and denotes the positive real n th root. A negative real number − x has no real-valued square roots, but when x is treated as a complex number it has two imaginary square roots, + i x {\displaystyle +i{\sqrt {x}}} and − i x {\displaystyle -i{\sqrt {x ...
The hydroxyl radical can damage virtually all types of macromolecules: carbohydrates, nucleic acids , lipids (lipid peroxidation) and amino acids (e.g. conversion of Phe to m-Tyrosine and o-Tyrosine). The hydroxyl radical has a very short in vivo half-life of approximately 10 −9 seconds and a high reactivity. [5]
In chemistry, a radical clock is a chemical compound that assists in the indirect methodology to determine the kinetics of a free-radical reaction. The radical-clock compound itself reacts at a known rate, which provides a calibration for determining the rate of another reaction.
A trivalent group 14 radical (also known as a trivalent tetrel radical) is a molecule that contains a group 14 element (E = C, Si, Ge, Sn, Pb) with three bonds and a free radical, having the general formula of R 3 E•. Such compounds can be categorized into three different types, depending on the structure (or equivalently the orbital in which ...
As an odd-electron species, CH is a radical. The ground state is a doublet (X 2 Π). The first two excited states are a quartet (with three unpaired electrons) (a 4 Σ −) and a doublet (A 2 Δ). The quartet lies at 71 kJ/mol above the ground state. [5] Reactions of the doublet radical with non-radical species involves insertion or addition ...
The charge separation in the isocyano radical is similar to that of carbon monoxide. • CN has a dipole moment of 1.45 debyes and a 2 Σ + ground electronic state. The selection rules are: + = + = where N is the angular momentum, S is the electric spin, and I = 1 is the nuclear spin of 14 N. [2]
The hydroperoxyl radical, also known as the hydrogen superoxide, is the protonated form of superoxide with the chemical formula HO 2, also written HOO •. This species plays an important role in the atmosphere and as a reactive oxygen species in cell biology.