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Printable version; Page information; Get shortened URL; Download QR code; In other projects Appearance. ... Di-tert-butyl ether chemical structure: Date: 22 April 2007:
Print/export Download as PDF; Printable version; In other projects Wikimedia Commons; Wikidata item; Appearance. ... Di-tert-butyl ether is a tertiary ether, ...
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Print/export Download as PDF; Printable version; In other projects Wikimedia Commons; ... Di-tert-butyl ether; Di(propylene glycol) methyl ether; Dibutyl ether;
Each HHB of the tert-butyl network were calculated (in absence of steric repulsion) to contribute 0.7 kcal/mol of stabilization. Calculations with one of the tert-butyl substituents with a methyl, ethyl, or isopropyl group result in net repulsion due to the loss of HHBs. [26] In total, this forms the basis of the corset effect. [5]
Print/export Download as PDF; Printable version; In other projects Wikidata item; ... Di-n-propyl ether; Di-tert-butyl ether; Dibutyl ether; Diethyl ether; Diglycidyl ...
Dibutyl ether is a chemical compound belonging to the ether family with the molecular formula of C 8 H 18 O. It is colorless, volatile, and flammable liquid and has peculiar ethereal smell. Liquid dibutyl ether is lighter than water. On the other hand, the vapor is heavier than air.
The tert-butoxide is a strong, non-nucleophilic base in organic chemistry. It readily abstracts acidic protons from substrates, but its steric bulk inhibits the group from participating in nucleophilic substitution, such as in a Williamson ether synthesis or an S N 2 reaction. tert-Butyl alcohol reacts with hydrogen chloride to form tert-butyl ...