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Key: AQEFLFZSWDEAIP ... Di-tert-butyl ether is a tertiary ether, primarily of theoretical interest as the simplest member of the class of di-tertiary ethers. See also
Di-tert-butyl ether chemical structure: Date: 22 April 2007: Source: Originally from en.wikipedia: Author: The original uploader was Wolfmankurd at English Wikipedia ...
Di-tert-butyl ether; Dibutyl ether; 2-Ethylhexanol; Octanols. 1-Octanol; 2-Octanol; 3-Octanol This page was last edited on 8 January 2025, at ...
Each HHB of the tert-butyl network were calculated (in absence of steric repulsion) to contribute 0.7 kcal/mol of stabilization. Calculations with one of the tert-butyl substituents with a methyl, ethyl, or isopropyl group result in net repulsion due to the loss of HHBs. [26] In total, this forms the basis of the corset effect. [5]
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Dibutyl ether is a chemical compound belonging to the ether family with the molecular formula of C 8 H 18 O. It is colorless, volatile, and flammable liquid and has peculiar ethereal smell. Liquid dibutyl ether is lighter than water. On the other hand, the vapor is heavier than air.
The tert-butoxide is a strong, non-nucleophilic base in organic chemistry. It readily abstracts acidic protons from substrates, but its steric bulk inhibits the group from participating in nucleophilic substitution, such as in a Williamson ether synthesis or an S N 2 reaction. tert-Butyl alcohol reacts with hydrogen chloride to form tert-butyl ...
Methyl nitrate is also the product of the oxidation of some organic compounds in the presence of nitrogen oxides and chlorine, namely chloroethane or di-tert-butyl ether, while also producing nitromethane. [6] Oxidation of nitromethane using nitrogen dioxide in an inert atmosphere can also yield methyl nitrate. [7]