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Being a solid highly soluble in water (545 g/L at 25 °C), [2] urea is much easier and safer to handle and store than the more irritant, caustic and hazardous ammonia (NH 3), so it is the reactant of choice. Trucks and cars using these catalytic converters need to carry a supply of diesel exhaust fluid, also sold as AdBlue, a solution of urea ...
Ammonia volatilization reduces the economic efficiency of agricultural cropping systems. Either yield will be reduced or additional costs will be incurred from additional nitrogen fertilizer. The amount of ammonia volatilization depends on several environmental factors, including temperature, pH, and the soil water content.
Ammonia readily dissolves in water. In an aqueous solution, it can be expelled by boiling. The aqueous solution of ammonia is basic, and may be described as aqueous ammonia or ammonium hydroxide. [30] The maximum concentration of ammonia in water (a saturated solution) has a specific gravity of 0.880 and is often known as '.880 ammonia'. [31]
The urea cycle converts highly toxic ammonia to urea for excretion. [1] This cycle was the first metabolic cycle to be discovered by Hans Krebs and Kurt Henseleit in 1932, [2] [3] [4] five years before the discovery of the TCA cycle. The urea cycle was described in more detail later on by Ratner and Cohen.
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/100 ml), unless shown otherwise. The substances are listed in alphabetical order.
DEF is a 32.5% solution of urea, (NH 2) 2 CO. When it is injected into the hot exhaust gas stream, the water evaporates and the urea thermally decomposes [13] to form ammonia (NH 3) and isocyanic acid (HNCO): (NH 2) 2 CO → NH 3 + HNCO. The isocyanic acid reacts with the water vapor and hydrolyses to carbon dioxide and ammonia: HNCO + H 2 O ...
Urea is the safest to store, but requires conversion to ammonia through thermal decomposition. [ 8 ] At the end of the process, the purified exhaust gasses are sent to the boiler or condenser or other equipment, or discharged into the atmosphere.
In animals, the main excretory products are carbon dioxide, ammonia (in ammoniotelics), urea (in ureotelics), uric acid (in uricotelics), guanine (in Arachnida), and creatine. The liver and kidneys clear many substances from the blood (for example, in renal excretion), and the cleared substances are then excreted from the body in the urine and ...