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Polymetallic nodules, also called manganese nodules, are mineral concretions on the sea bottom formed of concentric layers of iron and manganese hydroxides around a core. As nodules can be found in vast quantities, and contain valuable metals, deposits have been identified as a potential economic interest. [ 1 ]
It is found mostly in the bones, but also the liver, kidneys, and brain. [9] In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. It is familiar in the laboratory in the form of the deep violet salt potassium permanganate. It occurs at the active sites in some enzymes. [10]
Nodule is also used for widely scattered concretionary lumps of manganese, cobalt, iron, and nickel found on the floors of the world's oceans. This is especially true of manganese nodules. Manganese and phosphorite nodules form on the seafloor and are syndepositional in origin. Thus, technically speaking, they are concretions instead of nodules ...
Generally, exposure to ambient manganese air concentrations in excess of 5 micrograms Mn/m 3 can lead to manganese-induced symptoms. [ 3 ] In initial stages of manganism, neurological symptoms consist of reduced response speed, irritability, mood changes, and compulsive behaviors. [ 4 ]
The nodules form in a manner similar to pearls; there is a central object around which concentric layers are slowly deposited, causing the nodule to grow over time. The composition of the nodules can vary somewhat depending on their location and the conditions of their formation, but they are usually dominated by manganese- and iron oxides.
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Manganese precipitates in soils in the form of manganese-iron oxide minerals, which promote nutrient and organic matter accumulation due to their high surface area. Manganese is the tenth most abundant metal in the Earth's crust, making up approximately 0.1% of the total composition, or about 0.019 mol kg −1 , which is found mostly in the ...
Manganese(IV) oxide is a blackish or brown solid occurs naturally as the mineral pyrolusite, which is the main ore of manganese and a component of manganese nodules. The principal use for MnO 2 is for dry-cell batteries, such as the alkaline battery and the zinc–carbon battery. [6] Manganese(VII) oxide is dark green in its crystalline form.