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Polycarbonate has a glass transition temperature of about 147 °C (297 °F), [8] so it softens gradually above this point and flows above about 155 °C (311 °F). [9] Tools must be held at high temperatures, generally above 80 °C (176 °F) to make strain-free and stress-free products.
A polycarbonate is an oxocarbon dianion consisting of a chain of carbonate units, where successive carbonyl groups are directly linked to each other by shared additional oxygen atoms. That is, they are the conjugate bases of polycarbonic acids , the conceptual anhydrides of carbonic acid , or polymers of carbon dioxide .
The Flory–Fox equation relates the number-average molecular weight, M n, to the glass transition temperature, T g, as shown below: =, where T g,∞ is the maximum glass transition temperature that can be achieved at a theoretical infinite molecular weight and K is an empirical parameter that is related to the free volume present in the polymer sample.
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In this equation, k is the number of monomers in the chain, [1] and 0<a<1 is an empirically determined constant related to the fraction of unreacted monomer remaining. [ 2 ] The form of this distribution implies is that shorter polymers are favored over longer ones -the chain length is geometrically distributed .
If a gaseous emission sample is analyzed and found to contain water vapor and a pollutant concentration of say 40 ppmv, then 40 ppmv should be designated as the "wet basis" pollutant concentration. The following equation can be used to correct the measured "wet basis" concentration to a "dry basis" concentration: [3]
An Arkansas couple has given up their wedding fund to help an injured dog in need. Dylan McCay and his fiancé Emily Roberts revealed they used the money to pay for reconstructive surgery on a ...
The degree of polymerization, or DP, is the number of monomeric units in a macromolecule or polymer or oligomer molecule. [1] [2] [3]For a homopolymer, there is only one type of monomeric unit and the number-average degree of polymerization is given by ¯ ¯ = ¯, where ¯ is the number-average molecular weight and is the molecular weight of the monomer unit.