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For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
The ΔH° form undergoes discontinuities at a phase transition temperatures of the constituent element(s) and the compound. The enthalpy change for any standard reaction is designated ΔH° rx. Standard molar heat of formation of ZnBr 2 (c,l) from the elements, showing discontinuities at transition temperatures of the elements and the compound.
Periodic tables usually at least show the elements' symbols; many also provide supplementary information about the elements, either via colour-coding or as data in the cells. The above table shows the names and atomic numbers of the elements, and also their blocks, natural occurrences and standard atomic weights. For the short-lived elements ...
The enthalpy of formation of one mole of ethane gas refers to the reaction 2 C (graphite) + 3 H 2 (g) → C 2 H 6 (g). Standard enthalpy of hydrogenation is defined as the enthalpy change observed when one mole of an unsaturated compound reacts with an excess of hydrogen to become fully saturated.
(The heat change at constant pressure is called the enthalpy change; in this case the widely tabulated enthalpies of formation are used.) A related term is the heat of combustion, which is the chemical energy released due to a combustion reaction and of interest in the study of fuels.
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.3, Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements and Inorganic Compounds
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
The molar heat capacity is the heat capacity per unit amount (SI unit: mole) of a pure substance, and the specific heat capacity, often called simply specific heat, is the heat capacity per unit mass of a material. Heat capacity is a physical property of a substance, which means that it depends on the state and properties of the substance under ...