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4-Methylpyridine is both isolated from coal tar and is synthesized industrially. It forms via the reaction of acetaldehyde and ammonia in the presence of an oxide catalyst. The method also affords some 2-methylpyridine. 4-Methylpyridine is of little intrinsic value but is a precursor to other commercially significant species, often of medicinal ...
4-Methylpyridine, γ-picoline, 4-picoline [108-89-4] ... The CAS number of an unspecified picoline isomer is [1333-41-1]. The methyl group in 2- and 4- picolines is ...
The Chichibabin pyridine synthesis (/ ˈ tʃ iː tʃ iː ˌ b eɪ b iː n /) is a method for synthesizing pyridine rings. The reaction involves the condensation reaction of aldehydes, ketones, α,β-Unsaturated carbonyl compounds, or any combination of the above, with ammonia. [1]
For comparison, crystalline benzene is also orthorhombic, with space group Pbca, a = 729.2 pm, b = 947.1 pm, c = 674.2 pm (at 78 K), but the number of molecules per cell is only 4. [18] This difference is partly related to the lower symmetry of the individual pyridine molecule (C 2v vs D 6h for benzene).
trans-[MCl 2 (pyridine) 4] n+ is a common type of transition metal pyridine complex. Chloro(pyridine)cobaloxime. Crabtree's catalyst.. Owing to the relatively wide C-N-C angle, the 2,6-hydrogen atoms interfere with the formation of [M(py) 6] z complexes.
[4] σ-adduct (Meisenheimer adduct) formation; Evidence indicates that before addition of the amino group, the ring nitrogen atom is sorbed onto the surface of sodium amide and the sodium cation forms a coordination complex. [3] This increases the δ+ on the α-carbon atom, thus 1,2-addition of sodium amide is favored over 1,4-addition.
Brooker's merocyanine (1-methyl-4-[(oxocyclohexadienylidene)ethylidene]-1,4-dihydropyridine, MOED) [1] is an organic dye belonging to the class of merocyanines. MOED is notable for its solvatochromic properties, meaning it changes color depending on the solvent in which it is dissolved.
This colourless, oily liquid is derived from pyridine by replacement of the two H atoms with tert-butyl groups. ... and 2,6-di-tert-butyl-4-methylpyridine. [4] See also