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Classically we have for the angular momentum =. This is the same in quantum mechanics considering and as operators. Classically, an infinitesimal rotation of the vector = (,,) about the -axis to ′ = (′, ′,) leaving unchanged can be expressed by the following infinitesimal translations (using Taylor approximation):
The quantum rotor model is a mathematical model for a quantum system. It can be visualized as an array of rotating electrons which behave as rigid rotors that interact through short-range dipole-dipole magnetic forces originating from their magnetic dipole moments (neglecting Coulomb forces ).
Rotation formalisms are focused on proper (orientation-preserving) motions of the Euclidean space with one fixed point, that a rotation refers to.Although physical motions with a fixed point are an important case (such as ones described in the center-of-mass frame, or motions of a joint), this approach creates a knowledge about all motions.
The rotation operator gates (), and () are the analog rotation matrices in three Cartesian axes of SO(3), [c] along the x, y or z-axes of the Bloch sphere projection. As Pauli matrices are related to the generator of rotations, these rotation operators can be written as matrix exponentials with Pauli matrices in the argument.
The path integral formulation is a description in quantum mechanics that generalizes the stationary action principle of classical mechanics.It replaces the classical notion of a single, unique classical trajectory for a system with a sum, or functional integral, over an infinity of quantum-mechanically possible trajectories to compute a quantum amplitude.
Quantum tomography is a process by which, given a set of data representing the results of quantum measurements, a density matrix consistent with those measurement results is computed. [ 25 ] [ 26 ] When analyzing a system with many electrons, such as an atom or molecule , an imperfect but useful first approximation is to treat the electrons as ...
The phase-space formulation is a formulation of quantum mechanics that places the position and momentum variables on equal footing in phase space.The two key features of the phase-space formulation are that the quantum state is described by a quasiprobability distribution (instead of a wave function, state vector, or density matrix) and operator multiplication is replaced by a star product.
Pure rotation spectrum of atmospheric water vapour measured at Mauna Kea (33 cm −1 to 100 cm −1) The quantum number J refers to the total angular momentum, as before. Since there are three independent moments of inertia, there are two other independent quantum numbers to consider, but the term values for an asymmetric rotor cannot be ...