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For example, chlorine(V) has two valence electrons so it can accommodate three electron pairs from bonds with oxide ions. The charge on the ion is +5 − 3 × 2 = −1, and so the formula is ClO − 3. The structure of the ion is predicted by VSEPR theory to be pyramidal
An oxide (/ ˈ ɒ k s aɪ d /) is a chemical compound containing at least one oxygen atom and one other element [1] in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of –2) of oxygen, an O 2– ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials ...
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Cations and anions are also typically discrete and can be depicted unambiguously. For simple structures, say <10 atoms, it is helpful to depict all atoms explicitly. For more complex molecules, most hydrogen atoms attached to carbon are omitted, and carbon atoms are represented by vertices.
The perovskite structure is frequently found for ternary oxides formed with one large (A) and one small cation (B). In this structure, there is a simple cubic array of B cations, with the A cations occupying the center of the cube, and the oxide atoms are sited at the center of the 12 edges of the simple cube. [8] [5] [6] [7]
Polyoxomolybdates include the wheel-shaped molybdenum blue anions and spherical keplerates. The cluster [Mo 154 O 420 (NO) 14 (OH) 28 (H 2 O) 70] 20− consists of more than 700 atoms and is the size of a small protein. The anion is in the form of a tire (the cavity has a diameter of more than 20 Å) and an extremely large inner and outer surface.
2D diagram of mellitate C 12 O 6− 12, one of the oxocarbon anions. Black circles are carbon atoms, red circles are oxygen atoms. Each blue halo represents one half of a negative charge. In chemistry, an oxocarbon anion is a negative ion consisting solely of carbon and oxygen atoms, and therefore having the general formula C x O n−
Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.