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Polyphenols, such as bisphenol A or novolacs can react with epoxy resins at elevated temperatures (130–180 °C, 266–356 °F), normally in the presence of a catalyst. The resulting material has ether linkages and displays higher chemical and oxidation resistance than typically obtained by curing with amines or anhydrides.
The Dutch painting forger Han van Meegeren mixed phenol formaldehyde with his oil paints before baking the finished canvas, in order to fake the drying out of the paint over the centuries. [citation needed] Atmospheric re-entry spacecraft use phenol formaldehyde resin as a key component in ablative heat shields (e.g. AVCOAT on the Apollo modules).
The surface of the paint is engineered to be easily decontaminated after exposure to chemical warfare and biological warfare agents. The paint is also resistant to damage and removal by decontaminating solutions. Two-component systems (e.g. epoxy or polyester-based) are often employed. This coating is described in MIL-DTL-53072H.
Today, epoxy and the acrylic types predominate. The description and the generally touted advantages are as follows: Epoxy: Although aliphatic epoxy materials have been used, the majority of EPD epoxy types are based on aromatic epoxy polymers, most commonly based on polymerization of diglycidal ethers of bis phenol A. The polymer backbone may ...
Most coatings have four basic components. These are the resin, solvent, pigment and additive systems [5] but the resin or binder is the key ingredient. Continuing environmental legislation in many countries along with geopolitics such as oil production are ensuring that chemists are increasingly turning to waterborne technology for paint/coatings and since resins or binders are the most ...
The second most important part of FBE coatings is the curing agent or hardener. Curing agents react either with the epoxy ring or with the hydroxyl groups, along the epoxy molecular chain. Various types of curing agents, used in FBE manufacture, include dicyandiamide, aromatic amines, aliphatic diamines and organic acid anhydrides. [6]
[12] [13] From the 1990s onward, concern has been raised over the use of BADGE-based epoxy resins in the lining of some cans for foodstuffs, with the chemical being found to leach into foods. [ 12 ] [ 14 ] Bisphenol A Diglycidyl ether-based epoxy coatings are extensively used for coating the inside of cans which come into contact with food and ...
Phenol is so inexpensive that it also attracts many small-scale uses. It is a component of industrial paint strippers used in the aviation industry for the removal of epoxy, polyurethane and other chemically resistant coatings. [33] Due to safety concerns, phenol is banned from use in cosmetic products in the European Union [34] [35] and Canada ...
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