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In chemistry, the lever rule is a formula used to determine the mole fraction (x i) or the mass fraction (w i) of each phase of a binary equilibrium phase diagram.It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
Another type of binary phase diagram is a boiling-point diagram for a mixture of two components, i. e. chemical compounds. For two particular volatile components at a certain pressure such as atmospheric pressure , a boiling-point diagram shows what vapor (gas) compositions are in equilibrium with given liquid compositions depending on temperature.
The solidus is the locus of temperatures (a curve on a phase diagram) below which a given substance is completely solid (crystallized). The solidus temperature specifies the temperature below which a material is completely solid, [2] and the minimum temperature at which a melt can co-exist with crystals in thermodynamic equilibrium.
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125
Boiling-point diagram. The preceding equilibrium equations are typically applied for each phase (liquid or vapor) individually, but the result can be plotted in a single diagram. In a binary boiling-point diagram, temperature (T ) (or sometimes pressure) is graphed vs. x 1. At any given temperature (or pressure) where both phases are present ...
CALPHAD stands for Computer Coupling of Phase Diagrams and Thermochemistry, a methodology introduced in 1970 by Larry Kaufman, originally known as CALculation of PHAse Diagrams. [1] [2] [3] An equilibrium phase diagram is usually a diagram with axes for temperature and composition of a chemical system. It shows the regions where substances or ...
A binary phase diagram displaying solid solutions over the full range of relative concentrations. On a phase diagram a solid solution is represented by an area, often labeled with the structure type, which covers the compositional and temperature/pressure ranges. Where the end members are not isostructural there are likely to be two solid ...
The typical McCabe–Thiele diagram in Figure 1 uses a q-line representing a partially vaporized feed. Example q-line slopes are presented in Figure 2. The number of steps between the operating lines and the equilibrium line represents the number of theoretical plates (or equilibrium stages) required for the distillation. For the binary ...