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Chemical reactions: The rates of certain types of chemical reactions depend on the concentration of one or another reactant. Reactions whose rate depends only on the concentration of one reactant (known as first-order reactions) consequently follow exponential decay. For instance, many enzyme-catalyzed reactions behave this way.
First-order arithmetic; First-order condition; First-order hold, a mathematical model of the practical reconstruction of sampled signals; First-order inclusion probability; First Order Inductive Learner, a rule-based learning algorithm; First-order reduction, a very weak type of reduction between two computational problems; First-order resolution
A first order reaction depends on the concentration of only one reactant (a unimolecular reaction). Other reactants can be present, but their concentration has no effect on the rate. The rate law for a first order reaction is [] = [], The unit of k is s-1. [18]
For a first-order reaction, it has units of s −1. For that reason, it is often called frequency factor . According to collision theory , the frequency factor, A, depends on how often molecules collide when all concentrations are 1 mol/L and on whether the molecules are properly oriented when they collide.
A first-order approximation is to assume that the two different reaction products have different heat capacities. Incorporating this assumption yields an additional term c / T 2 in the expression for the equilibrium constant as a function of temperature.
In mathematics, the method of characteristics is a technique for solving partial differential equations.Typically, it applies to first-order equations, though in general characteristic curves can also be found for hyperbolic and parabolic partial differential equation.
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[A] can provide intuitive insight about the order of each of the reagents. If plots of v / [A] vs. [B] overlay for multiple experiments with different-excess, the data are consistent with a first-order dependence on [A]. The same could be said for a plot of v / [B] vs. [A]; overlay is consistent with a first-order dependence on [B].