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The tert-butoxide is a strong, non-nucleophilic base in organic chemistry. It readily abstracts acidic protons from substrates, but its steric bulk inhibits the group from participating in nucleophilic substitution, such as in a Williamson ether synthesis or an S N 2 reaction. tert-Butyl alcohol reacts with hydrogen chloride to form tert-butyl ...
The American Kennel Club (AKC) is a registry of purebred dog pedigrees in the United States. In addition to maintaining its pedigree registry, this kennel club also promotes and sanctions events for purebred dogs, including the Westminster Kennel Club Dog Show, an annual event which predates the official forming of the AKC, the National Dog Show and the AKC National Championship.
The King Charles Spaniel (also known as the English Toy Spaniel) is a small dog breed of the spaniel type. In 1903, The Kennel Club combined four separate toy spaniel breeds under this single title. The breed was originally created to hunt and kill bobcats, lynx and weasels.
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
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The Cavalier King Charles Spaniel and the English Toy Spaniel can often be confused with each other. In the United Kingdom, the English Toy Spaniel is called the King Charles Spaniel, while in the United States, one of the colours of the Toy Spaniel is known as King Charles. The two breeds share similar history and only diverged from each other ...
A Cavalier King Charles Spaniel, one of the dog breeds featured in Pedigree Dogs Exposed. The organisation was criticised in an August 2008 BBC programme Pedigree Dogs Exposed for allowing breed standards, judging standards and breeding practices which are said to compromise the health of purebred dogs. [39]
Name Picture Parent breeds and notes American Staghound: Cross of different sighthound breeds; bred in the United States as hunting dogs. [1]Beaglier: Cross of a Beagle and a Cavalier King Charles Spaniel; first deliberately bred in the 1990s by designer dog breeders in Australia as a companion dog with the aim of reducing the scent-hunting drive common in Beagles.
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