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These spaniels became great favourites of the British monarchs. King Charles I (1600–1649) had a spaniel as a young boy. Owing to Queen Victoria’s spaniel Dash (1830-40), however, the spaniel model enjoyed a surge in popularity in the 1840s which lasted through her reign. [13] Not all dog models were based solely on the spaniel.
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
tert-Butyl alcohol is used as a solvent, ethanol denaturant, paint remover ingredient, and gasoline octane booster and oxygenate.It is a chemical intermediate used to produce methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by reaction with methanol and ethanol, respectively, and tert-butyl hydroperoxide (TBHP) by reaction with hydrogen peroxide.
The average price was lower than that paid by Bismarck. In 1899, the price ranged between $50 and $200 for a King Charles or Blenheim, [32] with the Ruby and Prince Charles Spaniel ranging between $50 and $150. [33] [34] Anne Brontë's "Flossy", given to her by the Robinson children when she left her governorship of them, was a King Charles ...
The Cavalier King Charles Spaniel and the English Toy Spaniel can often be confused with each other. In the United Kingdom, the English Toy Spaniel is called the King Charles Spaniel, while in the United States, one of the colours of the Toy Spaniel is known as King Charles. The two breeds share similar history and only diverged from each other ...
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The repulsion between an axial t-butyl group and hydrogen atoms in the 1,3-diaxial position is so strong that the cyclohexane ring will revert to a twisted boat conformation. The strain in cyclic structures is usually characterized by deviations from ideal bond angles ( Baeyer strain ), ideal torsional angles ( Pitzer strain ) or transannular ...
Just check out this Cavalier King Charles Spaniel owner's tips for a clean, tear-free dog! I don't need any reminders of how precious Cavalier King Charles Spaniels are, but this video was magical ...
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