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Chlorodifluoromethane or difluoromonochloromethane is a hydrochlorofluorocarbon ... The pressure-enthalpy properties of R22, ... MSDS from DuPont;
From 1930 to 1935, they developed dichlorodifluoromethane (CCl 2 F 2 or R12), trichlorofluoromethane (CCl 3 F or R11), chlorodifluoromethane (CHClF 2 or R22), trichlorotrifluoroethane (CCl 2 FCClF 2 or R113), and dichlorotetrafluoroethane (CClF 2 CClF 2 or R114), through Kinetic Chemicals which was a joint venture between DuPont and General ...
R22 Harmful if swallowed R23 Toxic by inhalation R24 Toxic in contact with skin R25 Toxic if swallowed R26 Very toxic by inhalation R27 Very toxic in contact with skin R28 Very toxic if swallowed R29 Contact with water liberates toxic gas. R30 Can become highly flammable in use R31 Contact with acids liberates toxic gas R32
Chlorodifluoromethane (R-22 or HCFC-22), a type of Freon. [9] [10] Dichlorodifluoromethane (R-12 or CFC-12), the most commonly used Freon brand refrigerant prior to its ban in many countries in 1996 and total ban in 2010. 1,1,1,2-Tetrafluoroethane (R-134a or HFC-134a), one of the main replacements for the formerly widespread R-12.
CFCs and HCFCs are usually produced by halogen exchange starting from chlorinated methanes and ethanes. Illustrative is the synthesis of chlorodifluoromethane from chloroform: HCCl 3 + 2 HF → HCF 2 Cl + 2 HCl. Brominated derivatives are generated by free-radical reactions of hydrochlorofluorocarbons, replacing C-H bonds with C-Br bonds.
For example, R-22 has one carbon atom, one hydrogen atom (2−1 = 1), two fluorine atoms, and one chlorine atom (4−2−1 = 1), so it is chlorodifluoromethane, while R-134 has two carbon atoms (2−1 = 1), two hydrogen atoms (3−1 = 2), four fluorine atoms, and no chlorine atoms (6−2−4 = 0), so it is one of the tetrafluoroethanes. This ...
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Chlorodifluoromethane (R-22), for example, has an ODP of 0.05. CFC 11, or R-11 has the maximum potential amongst chlorocarbons because of the presence of three chlorine atoms in the molecule. The first proposal of ODP came from Wuebbles in 1983.