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A cooling curve of naphthalene from liquid to solid. A cooling curve is a line graph that represents the change of phase of matter, typically from a gas to a solid or a liquid to a solid. The independent variable (X-axis) is time and the dependent variable (Y-axis) is temperature. [1] Below is an example of a cooling curve used in castings.
The cooling produced in the Joule–Thomson expansion makes it a valuable tool in refrigeration. [8] [20] The effect is applied in the Linde technique as a standard process in the petrochemical industry, where the cooling effect is used to liquefy gases, and in many cryogenic applications (e.g. for the production of liquid oxygen, nitrogen, and ...
The cooling cycle proceeds in several steps: The gas is compressed, which adds external energy into the gas, to give it what is needed for running through the cycle. Linde's US patent gives an example with the low side pressure of 25 standard atmospheres (370 psi; 25 bar) and high side pressure of 75 standard atmospheres (1,100 psi; 76 bar).
The first and second law of thermodynamics are the most fundamental equations of thermodynamics. They may be combined into what is known as fundamental thermodynamic relation which describes all of the changes of thermodynamic state functions of a system of uniform temperature and pressure.
Many gases can be put into a liquid state at normal atmospheric pressure by simple cooling; a few, such as carbon dioxide, require pressurization as well. Liquefaction is used for analyzing the fundamental properties of gas molecules (intermolecular forces), or for the storage of gases, for example: LPG , and in refrigeration and air conditioning .
The specific cooling rate that is necessary to avoid the formation of pearlite is a product of the chemistry of the austenite phase and thus the alloy being processed. The actual cooling rate is a product of both the quench severity, which is influenced by quench media, agitation, load (quenchant ratio, etc.), and the thickness and geometry of ...
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We assume the expansion occurs without exchange of heat (adiabatic expansion). Doing this work , air inside the cylinder will cool to below the target temperature. To return to the target temperature (still with a free piston), the air must be heated, but is no longer under constant volume, since the piston is free to move as the gas is reheated.