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Roughly 2% of all hydrocarbons fixed in photosynthesis are converted into flavonoids and their derivatives, such as the anthocyanins. Not all land plants contain anthocyanin; in the Caryophyllales (including cactus, beets, and amaranth), they are replaced by betalains. Anthocyanins and betalains have never been found in the same plant. [10] [11]
Delphinidin (also delphinidine [1] [2]) is an anthocyanidin, a primary plant pigment, and also an antioxidant. [3] Delphinidin gives blue hues to flowers in the genera Viola and Delphinium. It also gives the blue-red color of the grape variety Cabernet Sauvignon, and can be found in cranberries and Concord grapes as well as pomegranates, [4 ...
Protocyanin is a blue pigment of cornflower (Centaurea cyanus). It is composed from succinylcyanin (anthocyanin), malonylflavone (co-pigment), iron and magnesium anions, and two calcium ions to stabilize the complex. Interesting is that the same anthocyanin when is not in complex with the metal ions is present in red rose petals. [8]
In bryophytes, anthocyanins are usually based on 3-desoxyanthocyanidins located in the cell wall. A new anthocyanidin, riccionidin A, has been isolated from the liverwort Ricciocarpos natans . It could be derived from 6,7,2′,4′,6′-pentahydroxyflavylium, having undergone ring closure of the 6’ -hydroxyl at the 3-position.
Blue color inflorescences of Hydrangea macrophylla. A metalloanthocyanin is a chemical complex giving color to petals of certain plants.. These complexes are self-assembled, supramolecular metal complex pigment composed of stoichiometric amounts of anthocyanins, flavones, and metal ions.
The generic garden peony. Peonidin is an O-methylated anthocyanidin derived from Cyanidin, and a primary plant pigment. Peonidin gives purplish-red hues to flowers such as the peony, from which it takes its name, and roses. It is also present in some blue flowers, such as the morning glory.
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In Ipomoea tricolor 'Heavenly Blue', the colour of the flower changes during blossom according to an increase in vacuolar pH. [ 11 ] [ 12 ] [ 13 ] This shift, from red to blue, is induced by chemical modifications affecting the anthocyanin molecules present in the petals.