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The optical spectrum of this d 6 octahedral complex exhibits an intense absorption near 250 nm corresponding to a transition from ligand σ MO to the empty e g MO. In IrBr 6 2−, which is a d 5 complex, two absorptions, one near 600 nm and another near 270 nm, are observed. These are assigned as two LMCT bands, one to t 2g and another to e g.
They all have lower energy than the lowest-energy intense band for the Fe(II) complex Fe(CN) 6 2− found at 46000 cm −1. [13] The red shift with increasing oxidation state of the metal is characteristic of LMCT bands. Additionally, only A terms, which are temperature independent, should be involved in MCD structure for closed-shell species.
In chemistry, charge-transfer (CT) complex, or electron donor-acceptor complex, describes a type of supramolecular assembly of two or more molecules or ions. The assembly consists of two molecules that self-attract through electrostatic forces, i.e., one has at least partial negative charge and the partner has partial positive charge, referred ...
In chemistry, a molybdate is a compound containing an oxyanion with molybdenum in its highest oxidation state of +6: O − −Mo(=O) 2 −O −. Molybdenum can form a very large range of such oxyanions, which can be discrete structures or polymeric extended structures, although the latter are only found in the solid state.
For example, d-wave or triplet superconductor, or a Fulde–Ferrell–Larkin–Ovchinnikov superconductor. Ferromagnetic superconductor: Materials that display intrinsic coexistence of ferromagnetism and superconductivity. Charge-4e superconductor: A proposed state in which electrons are not bound as Cooper pairs but as quadruplets of electrons.
For example, the absorption spectrum for ethane shows a σ → σ* transition at 135 nm and that of water a n → σ* transition at 167 nm with an extinction coefficient of 7,000. Benzene has three aromatic π → π* transitions; two E-bands at 180 and 200 nm and one B-band at 255 nm with extinction coefficients respectively 60,000, 8,000 and 215.
An example of this would be the two Co coordination polymers of the [Re 6 S 8 (CN) 6] 4− cluster that contains water ligands that coordinate to the cobalt atoms. This originally orange solution turns either purple or green with the replacement of water with tetrahydrofuran , and blue upon the addition of diethyl ether.
For the 'small rings' (3- and 4- membered), the slow rates is a consequence of angle strain experienced at the transition state. Although three-membered rings are more strained, formation of aziridine is faster than formation of azetidine due to the proximity of the leaving group and nucleophile in the former, which increases the probability that they would meet in a reactive conformation.