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Dicalcium phosphate is the calcium phosphate with the formula CaHPO 4 and its dihydrate. The "di" prefix in the common name arises because the formation of the HPO 4 2– anion involves the removal of two protons from phosphoric acid, H 3 PO 4.
It is a conjugate acid of phosphate [PO 4] 3-and a conjugate base of dihydrogen phosphate [H 2 PO 4] −. It is formed when a pyrophosphate anion [P 2 O 7] 4− reacts with water H 2 O by hydrolysis, which can give hydrogenphosphate: [P 2 O 7] 4− + H 2 O ⇌ 2 [HPO 4] 2−
The general formula of a phosphoric acid is H n+2−2x P n O 3n+1−x, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure, between 0 and n + 2 / 2 . Pyrophosphate anion. Trimethyl orthophosphate.
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Solid HP(O)(OH) 2 has tetrahedral geometry about the central phosphorus atom, with a P−H bond of 132 pm, one P=O double bond of 148 pm and two longer P−OH single bonds of 154 pm. In common with other phosphorus oxides with P−H bonds (e.g. hypophosphorous acid and dialkyl phosphites ), [ 2 ] it exists in equilibrium with an extremely minor ...
P 4 + 4 OH − + 4 H 2 O → 4 H 2 PO − 2 + 2 H 2. Any phosphites produced in this step can be selectively precipitated out by treatment with calcium salts. The purified material is then treated with a strong, non-oxidizing acid (often sulfuric acid) to give the free hypophosphorous acid: H 2 PO − 2 + H + → H 3 PO 2. HPA is usually ...
This is done by adding H 2 O, OH −, e −, and/or H + to either side of the reaction until both atoms and charges are balanced. Consider the half reaction below: OH −, H 2 O, and e − can be used to balance the charges and atoms in basic conditions, as long as it is assumed that the reaction is in water.
These materials contain Ca 2+ combined with the polyphosphates, such as P 2 O 4− 7 and triphosphate P 3 O 5− 10: Dicalcium diphosphate (CAS#7790-76-3]: Ca 2 P 2 O 7; Calcium triphosphate (CAS# 26158-70-3): Ca 5 (P 3 O 10) 2