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Hydrogen fluoride is typically produced by the reaction between sulfuric acid and pure grades of the mineral fluorite: [14] CaF 2 + H 2 SO 4 → 2 HF + CaSO 4. About 20% of manufactured HF is a byproduct of fertilizer production, which generates hexafluorosilicic acid. This acid can be degraded to release HF thermally and by hydrolysis:
Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48-52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling point near room temperature.
If HF alone is electrolyzed, hydrogen forms at the cathode (positive part of the cell) and the fluoride ions remain in solution. After electrolysis, potassium fluoride remains in solution. [35] 2 HF 2 − → H 2 ↑ + F 2 ↑ + 2 F −. The modern version of the process uses steel containers as cathodes, while blocks of carbon are used as anodes.
Organofluorine compounds are pervasive. Many drugs, many polymers, refrigerants, and many inorganic compounds are made from fluoride-containing reagents. Often fluorides are converted to hydrogen fluoride, which is a major reagent and precursor to reagents. Hydrofluoric acid and its anhydrous form, hydrogen fluoride, are particularly important. [4]
Hydrogen and fluorine combine to yield hydrogen fluoride, in which discrete molecules form clusters by hydrogen bonding, resembling water more than hydrogen chloride. [127] [128] [129] It boils at a much higher temperature than heavier hydrogen halides and unlike them is miscible with water. [130] Hydrogen fluoride readily hydrates on contact ...
Fluorite is a major source of hydrogen fluoride, a commodity chemical used to produce a wide range of materials. Hydrogen fluoride is liberated from the mineral by the action of concentrated sulfuric acid: CaF 2 + H 2 SO 4 → CaSO 4 (s) + 2 HF. The resulting HF is converted into fluorine, fluorocarbons, and diverse fluoride materials. As of ...
In 1886, French chemist Henri Moissan, later a Nobel Prize winner, succeeded in making elemental fluorine by electrolyzing a mixture of potassium fluoride and hydrogen fluoride. Large-scale production and use of fluorine began during World War 2 as part of the Manhattan Project.
Electrochemical fluorination (ECF), or electrofluorination, is a foundational organofluorine chemistry method for the preparation of fluorocarbon -based organofluorine compounds. [1] The general approach represents an application of electrosynthesis. The fluorinated chemical compounds produced by ECF are useful because of their distinctive ...