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In the compound on the left, the base value is 214 nm (a heteroannular diene). This diene group has 4 alkyl substituents (labeled 1,2,3,4) and the double bond in one ring is exocyclic to the other (adding 5 nm for an exocyclic double bond). In the compound on the right, the diene is homoannular with 4 alkyl substituents.
More specifically, it is classified as a thermally allowed [4+2] cycloaddition with Woodward–Hoffmann symbol [π 4 s + π 2 s]. It was first described by Otto Diels and Kurt Alder in 1928. For the discovery of this reaction, they were awarded the Nobel Prize in Chemistry in 1950. Through the simultaneous construction of two new carbon ...
3 + 2 = 5 with apples, a popular choice in textbooks [1]. Addition (usually signified by the plus symbol, +) is one of the four basic operations of arithmetic, the other three being subtraction, multiplication, and division. [2]
Nucleophilic conjugate addition. Nucleophilic conjugate addition is a type of organic reaction. Ordinary nucleophilic additions or 1,2-nucleophilic additions deal mostly with additions to carbonyl compounds. Simple alkene compounds do not show 1,2 reactivity due to lack of polarity, unless the alkene is activated with special substituents.
In mathematics, the conjugate transpose, also known as the Hermitian transpose, of an complex matrix is an matrix obtained by transposing and applying complex conjugation to each entry (the complex conjugate of + being , for real numbers and ).
This reaction produced the 1,6-addition product 2 in 0% yield, the 1,6-addition product 3 in approximately 99% yield, and the 1,4-addition product 4 in less than 2% yield. This particular catalyst and set of reaction conditions led to the mostly regioselective and enantioselective 1,6-Michael addition of ethyl sorbate 1 to product 3 .
In the case of hexa-1,5-diene, the rearrangement is degenerate (the product is identical to the starting material), so K = 1 by necessity. In asymmetric dienes one often needs to consider the stereochemistry, which in the case of pericyclic reactions, such as the Cope rearrangement, can be predicted with the Woodward–Hoffmann rules and ...
The time is usually based on a 12-hour clock. A method to solve such problems is to consider the rate of change of the angle in degrees per minute. The hour hand of a normal 12-hour analogue clock turns 360° in 12 hours (720 minutes) or 0.5° per minute. The minute hand rotates through 360° in 60 minutes or 6° per minute. [1]
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