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Chromic acid is capable of oxidizing many kinds of organic compounds and many variations on this reagent have been developed: Chromic acid in aqueous sulfuric acid and acetone is known as the Jones reagent, which will oxidize primary and secondary alcohols to carboxylic acids and ketones respectively, while rarely affecting unsaturated bonds. [12]
In 1983, a tank at the E.C Electroplating property malfunctioned and spilled chromic acid into the groundwater underneath the property that subsequently spread to the surrounding area. The contamination presented a health risk to Garfield residents in the area due to exposure to hexavalent chromium, a toxic form of chromium. The site was ...
The composition of CCA products is usually described in terms of the mass percentages of chromium trioxide or "chromic acid" CrO 3, arsenic pentoxide As 2 O 5, and copper(II) oxide CuO. [3] The preservative is applied as a water-based mixture containing 0.6–6.0% (by weight) of chromic acid, copper oxide, and arsenic acid (USDA, 1980), with pH ...
For aluminum, the chromate conversion bath can be simply a solution of chromic acid. The process is rapid (1–5 min), requires a single ambient temperature process tank and associated rinse, and is relatively trouble free. [2] As of 1995, Henkel's Alodine 1200s commercial formula for aluminum consisted of 50-60% chromic anhydride CrO
Hexavalent chromium is used in chrome plating, chromate coatings and primers, and in chromic acid. The maximum permitted concentrations in non-exempt products are 0.1% or 1000 ppm (except for cadmium, which is limited to 0.01% or 100 ppm) by weight.
Chromium(III) sulfate are commonly obtained from the wastes of chromate oxidations of various organic compounds. Anthraquinone and quinone are produced on large scale by the x treatment of respectively anthracene and phenol with chromic acid. A chromium(III) oxide byproduct is generated, which is readily extracted into sulfuric acid.
Chromyl chloride can be prepared by the reaction of potassium chromate or potassium dichromate with hydrogen chloride in the presence of concentrated sulfuric acid, followed by distillation. [3] [4] K 2 Cr 2 O 7 + 6 HCl → 2 CrO 2 Cl 2 + 2 KCl + 3 H 2 O. The sulfuric acid serves as a dehydration agent.
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