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Hypochlorite salts formed by the reaction between chlorine and alkali and alkaline earth metal hydroxides. The reaction is performed at close to room temperature to suppress the formation of chlorates. This process is widely used for the industrial production of sodium hypochlorite (NaClO) and calcium hypochlorite (Ca(ClO) 2).
The cathode reaction is: 2Na + + 2e − → 2Na (l) for an overall reaction of 2Na + + 2Cl − → 2Na (l) + Cl 2 (g) The calcium does not enter into the reaction because its reduction potential of -2.87 volts is lower than that of sodium, which is -2.38 volts. Hence the sodium ions are reduced to metallic form in preference to those of calcium ...
Near the end of the nineteenth century, E. S. Smith patented the chloralkali process: a method of producing sodium hypochlorite involving the electrolysis of brine to produce sodium hydroxide and chlorine gas, which then mixed to form sodium hypochlorite. [35] [33] [36] The key reactions are: 2 Cl − → Cl 2 + 2 e − (at the anode)
Example of a reduction–oxidation reaction between sodium and chlorine, with the OIL RIG mnemonic [1] Tetracyanoquinodimethane is an organic electron-acceptor. Electron acceptors participate in electron-transfer reactions. In this context, the oxidizing agent is called an electron acceptor and the reducing agent is called an electron donor.
The product of the process, sodium hypochlorite, provides 0.7% to 1% chlorine. Anything below the concentration of 1% chlorine is considered a non-hazardous chemical [according to whom?] although still a very effective disinfectant. The sodium hypochlorite produced is in the range of pH 6-7.5, relatively neutral in regards to acidity or
The process has a high energy consumption, for example around 2,500 kWh (9,000 MJ) of electricity per tonne of sodium hydroxide produced. Because the process yields equivalent amounts of chlorine and sodium hydroxide (two moles of sodium hydroxide per mole of chlorine), it is necessary to find a use for these products in the same proportion ...
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At 30 °C the relative reaction rates of primary, secondary and tertiary hydrogen atoms are in a relative ratio of approximately 1 to 3.25 to 4.43. The C-C bonds remain unaffected. [9] [10] Upon radiation the reaction involves alkyl and chlorine radicals following a chain reaction according to the given scheme:
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