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The German chemists Arthur Eichengrün and Theodore Becker invented the first soluble forms of cellulose acetate in 1903. [3] In 1904, Camille Dreyfus and his younger brother Henri performed chemical research and development on cellulose acetate in a shed in their father's garden in Basel, Switzerland, which was then a center of the dye ...
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown otherwise. The substances are listed in alphabetical order.
The most common way to prepare cellulose acetate phthalate consists of the reaction of a partially substituted cellulose acetate (CA) with phthalic anhydride in the presence of an organic solvent and a basic catalyst. The organic solvents widely used as reaction media for the phthaloylation of cellulose acetate are acetic acid, acetone, or ...
Cellulose acetate butyrate (CAB) is a mixed ester thermoplastic derivative of cellulose acetate that contains both acetate and butyrate functional groups. It has improved weathering resistance and lower moisture absorption compared to cellulose acetate.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Phthalates can plasticise ethyl cellulose, polyvinyl acetate phthalate (PVAP) and cellulose acetate phthalate (CAP), all of which are used to make enteric coatings for tablet and capsule medications. These coatings protect drugs from the acidity of the stomach, but allow their release and absorption in the intestines.
Cellulose acetate and cellulose triacetate are film- and fiber-forming materials that find a variety of uses. Nitrocellulose was initially used as an explosive and was an early film forming material. When plasticized with camphor, nitrocellulose gives celluloid. Cellulose Ether [54] derivatives include:
Triacetate is derived from cellulose by acetylating cellulose with acetic acid and/or acetic anhydride. Acetylation converts hydroxyl groups in cellulose to acetyl groups, which renders the cellulose polymer much more soluble in organic solvents. The cellulose acetate is dissolved in a mixture of dichloromethane and methanol for spinning.