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  2. Elimination reaction - Wikipedia

    en.wikipedia.org/wiki/Elimination_reaction

    Elimination reaction of cyclohexanol to cyclohexene with sulfuric acid and heat [1] An elimination reaction is a type of organic reaction in which two substituents are removed from a molecule in either a one- or two-step mechanism. [2] The one-step mechanism is known as the E2 reaction, and the two-step mechanism is known as the E1 reaction ...

  3. E1cB-elimination reaction - Wikipedia

    en.wikipedia.org/wiki/E1cB-elimination_reaction

    The E1cB mechanism is just one of three types of elimination reaction. The other two elimination reactions are E1 and E2 reactions. Although the mechanisms are similar, they vary in the timing of the deprotonation of the α-carbon and the loss of the leaving group. E1 stands for unimolecular elimination, and E2 stands for bimolecular elimination.

  4. Ubiquitin-activating enzyme - Wikipedia

    en.wikipedia.org/wiki/Ubiquitin-activating_enzyme

    Ubiquitin-activating enzymes, also known as E1 enzymes, catalyze the first step in the ubiquitination reaction, which (among other things) can target a protein for degradation via a proteasome. This covalent bond of ubiquitin or ubiquitin-like proteins to targeted proteins is a major mechanism for regulating protein function in eukaryotic ...

  5. Solvolysis - Wikipedia

    en.wikipedia.org/wiki/Solvolysis

    An example of a solvolysis reaction is the reaction of a triglyceride with a simple alcohol such as methanol or ethanol to give the methyl or ethyl esters of the fatty acid, as well as glycerol. This reaction is more commonly known as a transesterification reaction due to the exchange of the alcohol fragments.

  6. Reaction intermediate - Wikipedia

    en.wikipedia.org/wiki/Reaction_intermediate

    E1 and E2 are two different mechanisms for elimination reactions, and E1 involves a carbocation intermediate. In E1, a leaving group detaches from a carbon to form a carbocation reaction intermediate. Then, a solvent removes a proton, but the electrons used to form the proton bond form a pi bond, as shown in the pictured reaction on the right. [4]

  7. Dehydrohalogenation - Wikipedia

    en.wikipedia.org/wiki/Dehydrohalogenation

    CH 2 Cl-CH 2 Cl → CH 2 =CHCl + HCl. The resulting HCl can be reused in oxychlorination reaction. Thermally induced dehydrofluorinations are employed in the production of fluoroolefins and hydrofluoroolefins. One example is the preparation of 1,2,3,3,3-pentafluoropropene from 1,1,2,3,3,3-hexafluoropropane: CF 2 HCH(F)CF 3 → CHF=C(F)CF 3 + HF

  8. Ei mechanism - Wikipedia

    en.wikipedia.org/wiki/Ei_mechanism

    In organic chemistry, the E i mechanism (Elimination Internal/Intramolecular), also known as a thermal syn elimination or a pericyclic syn elimination, is a special type of elimination reaction in which two vicinal (adjacent) substituents on an alkane framework leave simultaneously via a cyclic transition state to form an alkene in a syn elimination. [1]

  9. Arrow pushing - Wikipedia

    en.wikipedia.org/wiki/Arrow_pushing

    Arrow pushing or electron pushing is a technique used to describe the progression of organic chemistry reaction mechanisms. [1] It was first developed by Sir Robert Robinson.In using arrow pushing, "curved arrows" or "curly arrows" are drawn on the structural formulae of reactants in a chemical equation to show the reaction mechanism.