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The higher heating value is experimentally determined in a bomb calorimeter. The combustion of a stoichiometric mixture of fuel and oxidizer (e.g. two moles of hydrogen and one mole of oxygen) in a steel container at 25 °C (77 °F) is initiated by an ignition device and the reactions allowed to complete.
Bomb calorimeter A bomb calorimeter is a type of constant-volume calorimeter used in measuring the heat of combustion of a particular reaction. Electrical energy is used to ignite the fuel; as the fuel is burning, it will heat up the surrounding air, which expands and escapes through a tube that leads the air out of the calorimeter.
Calorimetry requires that a reference material that changes temperature have known definite thermal constitutive properties. The classical rule, recognized by Clausius and Kelvin, is that the pressure exerted by the calorimetric material is fully and rapidly determined solely by its temperature and volume; this rule is for changes that do not involve phase change, such as melting of ice.
A reaction calorimeter is a calorimeter that measures the amount of energy released (in exothermic reactions) or absorbed (in endothermic reactions) by a chemical reaction. It does this by measuring the total change in temperature of an exact amount of water in a vessel.
Enthalpy of mixing is often calculated experimentally using calorimetry methods. A bomb calorimeter is created to be an isolated system with an insulated frame and a reaction chamber, and is used to transfer the heat of mixing into surrounding water for which the temperature is measured.
The Atwater system, [1] named after Wilbur Olin Atwater, or derivatives of this system are used for the calculation of the available energy of foods.The system was developed largely from the experimental studies of Atwater and his colleagues in the later part of the 19th century and the early years of the 20th at Wesleyan University in Middletown, Connecticut.
A calorimeter constant (denoted C cal) is a constant that quantifies the heat capacity of a calorimeter. [ 1 ] [ 2 ] It may be calculated by applying a known amount of heat to the calorimeter and measuring the calorimeter's corresponding change in temperature .
a Calorimeter in CERN. In experimental particle physics, a calorimeter is a type of detector that measures the energy of particles. Particles enter the calorimeter and initiate a particle shower in which their energy is deposited in the calorimeter, collected, and measured. The energy may be measured in its entirety, requiring total containment ...