Search results
Results from the WOW.Com Content Network
The world's first ice-calorimeter, used in the winter of 1782–83, by Antoine Lavoisier and Pierre-Simon Laplace, to determine the heat involved in various chemical changes; calculations which were based on Joseph Black's prior discovery of latent heat. These experiments mark the foundation of thermochemistry.
The higher heating value is experimentally determined in a bomb calorimeter. The combustion of a stoichiometric mixture of fuel and oxidizer (e.g. two moles of hydrogen and one mole of oxygen) in a steel container at 25 °C (77 °F) is initiated by an ignition device and the reactions allowed to complete.
A reaction calorimeter is a calorimeter that measures the amount of energy released (in exothermic reactions) or absorbed (in endothermic reactions) by a chemical reaction. It does this by measuring the total change in temperature of an exact amount of water in a vessel.
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the ...
Constant-temperature calorimeter, phase change calorimeter for example an ice calorimeter or any other calorimeter observing a phase change or using a gauged phase change for heat measurement. Constant-volume calorimeter, also called bomb calorimeter; Constant-pressure calorimeter, enthalpy-meter, or coffee cup calorimeter
The world's first ice-calorimeter, used in the winter of 1782–83, by Antoine Lavoisier and Pierre-Simon Laplace, to determine the heat evolved in various chemical changes; calculations which were based on Joseph Black's prior discovery of latent heat. These experiments mark the foundation of thermochemistry.
The enthalpy of a chemical system is essentially its energy. The enthalpy change ΔH for a reaction is equal to the heat q transferred out of (or into) a closed system at constant pressure without in- or output of electrical energy. Heat production or absorption in a chemical reaction is measured using calorimetry, e.g. with a bomb calorimeter.
Cone calorimeter stage while in use. Note that thermoplastic walls surround the apparatus, providing safe separation between the flame and the scientist. A cone calorimeter is an instrument used to study the behavior of fire in small samples of condensed phase materials.