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A thermodynamic system is a macroscopic object, the microscopic details of which are not explicitly considered in its thermodynamic description. The number of state variables required to specify the thermodynamic state depends on the system, and is not always known in advance of experiment; it is usually found from experimental evidence.
In the thermodynamics of equilibrium, a state function, function of state, or point function for a thermodynamic system is a mathematical function relating several state variables or state quantities (that describe equilibrium states of a system) that depend only on the current equilibrium thermodynamic state of the system [1] (e.g. gas, liquid, solid, crystal, or emulsion), not the path which ...
In equilibrium thermodynamics the state variables do not include fluxes because in a state of thermodynamic equilibrium all fluxes have zero values by definition. Equilibrium thermodynamic processes may involve fluxes but these must have ceased by the time a thermodynamic process or operation is complete bringing a system to its eventual ...
A central aim in equilibrium thermodynamics is: given a system in a well-defined initial equilibrium state, and given its surroundings, and given its constitutive walls, to calculate what will be the final equilibrium state of the system after a specified thermodynamic operation has changed its walls or surroundings.
In physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. [1] [2] Most modern equations of state are formulated in the Helmholtz free energy.
In mechanical systems, the position coordinates and velocities of mechanical parts are typical state variables; knowing these, it is possible to determine the future state of the objects in the system. In thermodynamics, a state variable is an independent variable of a state function.
The third law of thermodynamics states that a system's entropy approaches a constant value as the temperature approaches absolute zero. With the exception of non-crystalline solids , the entropy of a system at absolute zero is typically close to zero. [2]
The state postulate is a term used in thermodynamics that defines the given number of properties to a thermodynamic system in a state of equilibrium. It is also sometimes referred to as the state principle. [1] The state postulate allows a finite number of properties to be specified in order to fully describe a state of thermodynamic equilibrium.