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The equilibrium constant of a chemical reaction is ... of the dimensionless quantity. For example, for the equilibrium 2NO 2 ... used to calculate the value of ...
The reaction quotient plays a crucial role in understanding the direction and extent of a chemical reaction's progress towards equilibrium: Equilibrium condition: At equilibrium, the reaction quotient (Q) is equal to the equilibrium constant (K) for the reaction. This condition is represented as Q = K, indicating that the forward and reverse ...
The equilibrium expression above is a function of the concentrations [A], [B] etc. of the chemical species in equilibrium. The equilibrium constant value can be determined if any one of these concentrations can be measured.
For a reversible reaction, the equilibrium constant can be measured at a variety of temperatures. This data can be plotted on a graph with ln K eq on the y -axis and 1 / T on the x axis. The data should have a linear relationship, the equation for which can be found by fitting the data using the linear form of the Van 't Hoff equation
The extent of reaction is a useful quantity in computations with equilibrium reactions. [citation needed] Consider the reaction 2 A ⇌ B + 3 C. where the initial amounts are = , = , = , and the equilibrium amount of A is 0.5 mol. We can calculate the extent of reaction in equilibrium from its definition
The basis for the rule [3]: 122–126 is that equilibrium between phases places a constraint on the intensive variables. More rigorously, since the phases are in thermodynamic equilibrium with each other, the chemical potentials of the phases must be equal. The number of equality relationships determines the number of degrees of freedom.
The free concentrations are calculated by solving the equations of mass-balance, and the concentrations of the complexes are calculated using the equilibrium constant definitions. A quantity corresponding to the observed quantity can then be calculated using physical principles such as the Nernst potential or Beer-Lambert law which relate the ...
This raises the equilibrium quantity from Q 1 to the higher Q 2. (A movement along the curve is described as a "change in the quantity demanded" to distinguish it from a "change in demand", that is, a shift of the curve.) The increase in demand has caused an increase in (equilibrium) quantity. The increase in demand could come from changing ...