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Lamellae form during crystallization from the melt. The arrow shows the direction of temperature gradient. [5] Nucleation starts with small, nanometer-sized areas, where a result of heat motions in some chains or their segments occur parallel. Those seeds can either dissociate, if thermal motion destroys the molecular order, or grow further, if ...
Some polymer solutions also have a lower critical solution temperature (LCST) or lower bound to a temperature range of partial miscibility. As shown in the diagram, for polymer solutions the LCST is higher than the UCST, so that there is a temperature interval of complete miscibility, with partial miscibility at both higher and lower temperatures.
Polymers have both a melting temperature T m and a glass transition temperature T g. Above the T m, the polymer chains lose their molecular ordering and exhibit reptation, or mobility. Below the T m, but still above the T g, the polymer chains lose some of their long-range mobility and can form either crystalline or amorphous regions. In this ...
Liquid crystallinity in polymers may occur either by dissolving a polymer in a solvent (lyotropic liquid-crystal polymers) or by heating a polymer above its glass or melting transition point (thermotropic liquid-crystal polymers). [6] Liquid-crystal polymers are present in melted/liquid or solid form. [7]
In polymer physics, spherulites (from Greek sphaira = ball and lithos = stone) are spherical semicrystalline regions inside non-branched linear polymers. Their formation is associated with crystallization of polymers from the melt and is controlled by several parameters such as the number of nucleation sites, structure of the polymer molecules, cooling rate, etc. Depending on those parameters ...
The crystals are captured, stored, and sputter-coated with platinum at cryo-temperatures for imaging. The crystallization process appears to violate the second principle of thermodynamics. Whereas most processes that yield more orderly results are achieved by applying heat, crystals usually form at lower temperatures – especially by ...
Liquid crystals can consist of proteins, small molecules, or polymers, that can be manipulated to form cohesive order in a specific direction. [38] They exhibit liquid-like behavior in that they can flow, yet they can obtain close-to-crystal alignment. One feature of liquid crystals is their ability to spontaneously break symmetry. [39]
The temperature range offered by the PCM technology provides a new horizon for the building services and refrigeration engineers regarding medium and high temperature energy storage applications. The scope of this thermal energy application is wide-ranging of solar heating, hot water, heating rejection (i.e., cooling tower), and dry cooler ...