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4-Bromobenzaldehyde, or p-bromobenzaldehyde, is an organobromine compound with the formula BrC 6 H 4 CHO. It is one of three isomers of bromobenzaldehyde . [ 3 ] It displays reactivity characteristic of benzaldehyde and an aryl bromide .
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Methyl benzoate is an organic compound. It is an ester with the chemical formula C 6 H 5 COOCH 3, sometimes abbreviated as PhCO 2 Me, where Ph and Me are phenyl and methyl, respectively. Its structure is C 6 H 5 −C(=O)−O−CH 3. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents.
For example, nonylmagnesium bromide reacts with methyl p-chlorobenzoate to give p-nonylbenzoic acid, in the presence of Tris(acetylacetonato)iron(III) (Fe(acac) 3), after workup with NaOH to hydrolyze the ester, shown as follows. Without the Fe(acac) 3, the Grignard reagent would attack the ester group over the aryl halide. [21]
Methyl 4-iodobenzoate, or methyl p-iodobenzoate, is an organic compound with the formula IC 6 H 4 COOCH 3. [3] It is the methyl ester of 4-iodobenzoic acid , or may also be viewed as an iodinated derivative of methyl benzoate .
4-Methylbenzaldehyde is the aromatic aldehyde with the formula CH 3 C 6 H 4 CHO. It is a colorless liquid. It is a colorless liquid. Commercially available, it may be prepared from the Friedel-Crafts formylation of toluene with carbon monoxide and hydrogen chloride under Gattermann-Koch conditions .
Methyllithium is mainly used as the synthetic equivalent of the methyl anion synthon. For example, ketones react to give tertiary alcohols in a two-step process: Ph 2 CO + MeLi → Ph 2 C(Me)OLi Ph 2 C(Me)OLi + H + → Ph 2 C(Me)OH + Li + Nonmetal halides are converted to methyl compounds with methyllithium: PCl 3 + 3 MeLi → PMe 3 + 3 LiCl