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This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) ... Methanol [4] 0.79 64.7 Ethanol: 0.78 78.4 1.22 ... Formic acid: 101.0 2.4 8.0 –2.77 K b & K f [1 ...
Acetophenone is formed as a byproduct of the cumene process, the industrial route for the synthesis of phenol and acetone.In the Hock rearrangement of isopropylbenzene hydroperoxide, migration of a methyl group rather than the phenyl group gives acetophenone and methanol as a result of an alternate rearrangement of the intermediate:
Phenylacetone, also known as phenyl-2-propanone, is an organic compound with the chemical formula C 6 H 5 CH 2 COCH 3.It is a colorless oil that is soluble in organic solvents.It is a mono-substituted benzene derivative, consisting of an acetone attached to a phenyl group.
Note that the form of this formula as given is a fit to the Clausius–Clapeyron equation, which is a good theoretical starting point for calculating saturation vapor pressures: log 10 (P) = −(0.05223) a / T + b , where P is in mmHg, T is in kelvins, a = 38324, and b = 8.8017.
Chemical structure of 2-bromophenol. A bromophenol is an organic compound consisting of hydroxyl groups and bromine atoms bonded to a benzene ring. They may be viewed as hydroxyl derivatives of bromobenzene, or as brominated derivatives of phenol.
Reactions of phenanthrene typically occur at the 9 and 10 positions, including: Oxidation with chromic acid gives gives phenanthrenequinone. [11] Organic reduction to 9,10-dihydrophenanthrene with hydrogen gas and raney nickel [12] Electrophilic halogenation to 9-bromophenanthrene with bromine [13]
The methylation is carried out by contacting gaseous phenol and methanol at elevated temperatures in the presence of a solid acid catalyst: [2] [3] C 6 H 5 OH + 2 CH 3 OH → (CH 3) 2 C 6 H 3 OH + 2 H 2 O. Challenges associated with the production is the similarity of the boiling points of cresols and this xylenol.