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Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
L is the latent heat of vaporization at the temperature T, T C is the critical temperature, L 0 is the parameter that is equal to the heat of vaporization at zero temperature (T → 0), tanh is the hyperbolic tangent function. This equation was obtained in 1955 by Yu. I. Shimansky, at first empirically, and later derived theoretically.
The August equation describes a linear relation between the logarithm of the pressure and the reciprocal temp. This assumes a temperature-independent heat of vaporization. The Antoine equation allows an improved, but still inexact description of the change of the heat of vaporization with the temperature.
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
The Clausius–Clapeyron equation [8]: 509 applies to vaporization of liquids where vapor follows ideal gas law using the ideal gas constant and liquid volume is neglected as being much smaller than vapor volume V. It is often used to calculate vapor pressure of a liquid. [9]
is the heat flux from the gas to the droplet surface (J.s −1) is the latent heat of evaporation of the species considered (J.kg −1) Analytical expressions for the droplet vaporization rate, ˙, and for the heat flux are now derived. A single, pure, component droplet is considered and the gas phase is assumed to behave as an ideal gas.
The Joback method, often named Joback–Reid method, predicts eleven important and commonly used pure component thermodynamic properties from molecular structure only. It is named after Kevin G. Joback in 1984 [1] and developed it further with Robert C. Reid. [2] The Joback method is an extension of the Lydersen method [3] and uses very similar groups, formulas, and parameters for the three ...
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds